Educational resource

Amino acid abbreviations

The twenty proteinogenic (standard) amino acids are the building blocks of ribosomal peptides and the alphabet behind most sequences in this database. Each residue has a full name, a three-letter code, and a one-letter code.

Residue mass versus free amino-acid mass

The residue mass in the table below is the mass contributed when that amino acid is incorporated into a peptide chain: free amino-acid mass minus one water (H2O). It is not the mass of the free zwitterion in solution. Summing residue masses and adding back the terminal water (plus corrections for amides, disulfides, and other modifications) is the usual route to peptide molecular weight — see the molecular-weight guide.

Standard residue table

Monoisotopic residue masses below use common IUPAC elemental values and are typical inputs for high-resolution peptide calculations. Compound records on this site more often store average (chemical) molecular weight when the cited monograph does.

Name 3-letter 1-letter Side chain Residue mass (Da)
Alanine Ala A Methyl 71.03711
Arginine Arg R Guanidinium 156.10111
Asparagine Asn N Amide 114.04293
Aspartic acid Asp D Carboxylate 115.02694
Cysteine Cys C Thiol 103.00919
Glutamic acid Glu E Carboxylate 129.04259
Glutamine Gln Q Amide 128.05858
Glycine Gly G Hydrogen 57.02146
Histidine His H Imidazole 137.05891
Isoleucine Ile I sec-Butyl 113.08406
Leucine Leu L Isobutyl 113.08406
Lysine Lys K Butylammonium 128.09496
Methionine Met M Methyl thioether 131.04049
Phenylalanine Phe F Benzyl 147.06841
Proline Pro P Pyrrolidine 97.05276
Serine Ser S Hydroxymethyl 87.03203
Threonine Thr T Hydroxyethyl 101.04768
Tryptophan Trp W Indole 186.07931
Tyrosine Tyr Y Phenol 163.06333
Valine Val V Isopropyl 99.06841

Side-chain chemistry in brief

  • Nonpolar — Gly, Ala, Val, Leu, Ile, Met, Phe, Trp, Pro; often buried in folded structures.
  • Polar uncharged — Ser, Thr, Asn, Gln, Tyr, Cys (thiol); hydrogen-bonding and, for Cys, disulfide formation.
  • Acidic — Asp, Glu; contribute negative charge at physiological pH.
  • Basic — Lys, Arg, His; contribute positive charge (His near neutrality).

Ile and Leu share the same residue mass but differ in side-chain branching; they are distinct letters (I vs L) and must not be swapped in sequences.

Ambiguous and placeholder letters

  • X — unknown or non-canonical residue (explained in display notation on this site)
  • B — Asx (Asn or Asp); common in older sequencing; not used here
  • Z — Glx (Gln or Glu); not used here
  • J — Xle (Leu or Ile); not used here
  • U — selenocysteine; rare; would be noted explicitly if present
  • O — pyrrolysine; rare; would be noted explicitly if present

Beyond the twenty

Therapeutic and microbial peptides often include Aib (α-aminoisobutyric acid), ornithine, D-amino acids, N-methyl residues, pyroglutamate, and lipidated lysines. Those species are not interchangeable with a single standard letter. This database records them in display notation and in the modifications taxonomy rather than forcing a false 1-letter identity.